Hydrolysis of cellulose using heteropoly salts derivatives from H3PW12O40 with different redox properties as catalysts
نویسندگان
چکیده
منابع مشابه
Hydrolysis of cellulose to glucose by solid acid catalysts
As the main component of lignocelluloses, cellulose is a biopolymer consisting of many glucose units connected through β-1,4-glycosidic bonds. Breakage of the β-1,4-glycosidic bonds by acids leads to the hydrolysis of cellulose polymers, resulting in the sugar molecule glucose or oligosaccharides. Mineral acids, such as HCl and H2SO4, have been used in the hydrolysis of cellulose. However, they...
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heteropoly acids (hpa) and their salts have advantages as catalysts which make them both economically and environmentally attractive, strong br?nsted acidity, exhibiting fast reversible multi-electron redox transformations under rather mild conditions, very high solubility in polar solvents, fairly high thermal stability in the solid states, and efficient oxidizing ability, so that they are imp...
15 صفحه اولDevelopment and Evaluation of Thymol Microparticles Using Cellulose Derivatives as Controlled Release Dosage Form
Thymol, an important and advantageous component of many essential oils, has been applied as an antimicrobial agent in animals. To increase the duration of action of this compound in ruminants, it was decided here to prepare a controlled release carrier for thymol. Hydroxy propyl methyl cellulose (HPMC) and ethyl cellulose (EC) were used as the matrix polymer here. Mixtures of thymol with eight ...
متن کاملTetraalkylammonium Salts as Hydrogen-Bonding Catalysts.
Although the hydrogen-bonding ability of the α hydrogen atoms on tetraalkylammonium salts is often discussed with respect to phase-transfer catalysts, catalysis that utilizes the hydrogen-bond-donor properties of tetraalkylammonium salts remains unknown. Herein, we demonstrate hydrogen-bonding catalysis with newly designed tetraalkylammonium salt catalysts in Mannich-type reactions. The structu...
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Novel pyrazole derivatives 2-7 are synthesized by the reaction of 2-substituted 1,3-bis(dimethylamino)-trimethinium salts with phenyl hydrazine in acetonitrile as the solvent. This method has some advantages of high yields (78-85%), simplicity of the process and easy of control. The ultraviolet spectral behavior of the synthesized compounds is examined in CDCl3 and their structures were charact...
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ژورنال
عنوان ژورنال: Matéria (Rio de Janeiro)
سال: 2017
ISSN: 1517-7076
DOI: 10.1590/s1517-707620170003.0200